RHEOBYK 425 is a liquid, VOC-free rheology additive for aqueous systems, designed to adjust in-can viscosity and enhance anti-sagging and anti-settling properties. It provides pseudoplastic rheology, excellent sag resistance, and good pigment dispersion. This product is APEO-free, offers wide pH compatibility, and is ideal for waterborne coatings, inks, adhesives, and fabric softeners. It is part of the polyurethanes (PU) chemical family and is suitable for applications using spray methods, ensuring good gloss retention.

Chemical Family: Polyurethanes (PU)

Labeling Claims: Alkylphenol Ethoxylate (APEO)-free, Volatile Organic Compound (VOC)-free

Enhanced TDS

Identification & Functionality

Features & Benefits

Applications & Uses

Markets
Applications
Application Area
Application Method
Adhesive & Sealant End Applications
Coating End Applications
Home Care Applications
Ink & Toner End Applications
Use Level
0.1 - 2 % (Coatings industry), 1.0 - 3.0% (Detergents, cleaning and care products)
Coatings, Printing Inks, and Adhesives

Special Features and Benefits
The rheological effectiveness of RHEOBYK-425 is primarily based on the associative interaction with the dispersion particles of the aqueous binder and enables a highly pronounced pseudoplastic flow behavior. The urea modification of the additive also causes an increase in the rheological effect via hydrogen bonds. RHEOBYK-425 is VOC- and APEO-free, does not impair gloss, and its rheological effect is not dependent on the pH value.

Recommended Use
RHEOBYK-425 is suitable for all kinds of aqueous coatings, printing inks, and adhesives in order to improve the anti-sagging properties and set the required in-can viscosity of the formulation. The resulting increase in viscosity simultaneously improves the storage stability with reduced settling. When grinding pigment pastes, the additive can also increase the millbase viscosity and therefore improve the dispersion conditions.
For formulations with a considerably lower application viscosity (e.g. coatings for conventional spraying), it is recommended to use RHEOBYK-425 together with RHEOBYK-420 (or RHEOBYK-D 420 or RHEOBYK-7420 ES), as the anti-settling properties are much more pronounced.

Recommended Levels
0.1-2% additive (as supplied) based on the total formulation.
The above recommended levels can be used for orientation. Optimal levels are determined through a series of laboratory tests.

Incorporation and Processing Instructions
RHEOBYK-425 can be added to the formulation at any time during the production process; we recommend that it is post-added using a moderate shear force. If RHEOBYK-425 is to be used in pigment pastes to improve the dispersion conditions by increasing the millbase viscosity, it must be added directly to the millbase.
Due to its considerable rheological effectiveness, the additive may cause an immediate, very strong increase in viscosity and therefore make further processing more difficult. In this case, we recommend that it is prediluted. It can be diluted with just water (10 parts RHEOBYK-425 + 90 parts water) or also with a water/ co-solvent mix using a standard coalescent (e.g. 20 parts RHEOBYK-425 + 70 parts water + 10 parts coalescent). RHEOBYK-425 is highly viscous at low temperatures; predilution can also be helpful under these conditions. The storage stability of the diluted solutions should be tested on a case-by-case basis.

Detergents, Cleaning and Care Products

Special Features and Benefits
The rheological effectiveness of RHEOBYK-425 is based on associative interactions with the surfactant micelles in the system, and enables a highly pronounced pseudoplastic flow behavior. Furthermore, the urea modification of the additive causes an increase in the rheological effect via hydrogen bonds. The resulting flow behavior is ideal, for example, for preventing particles (e.g. encapsulated fragrances) from settling, without negatively impacting the residual emptying of the container.
RHEOBYK-425 is VOC and APEO-free. The additive is liquid and therefore easy to handle. Its thickening effect is not dependent upon the pH value. The anti-settling properties are more pronounced at pH values above 4.5. The compatibility with surfactants, including cationic surfactants, is extremely good. The rheological effectiveness of the associative thickener depends on the respective system composition.

Recommended Use
RHEOBYK-425 is used as a thickener and anti-settling additive in aqueous systems.
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Recommended Levels
0.1-1.0% additive (as supplied) based upon the total formulation, depending on the properties of the formulation to be achieved.
The above recommended levels can be used for orientation. Optimal levels are determined through a series of laboratory tests.

Incorporation and Processing Instructions
RHEOBYK-425 can be added to the formulation at any time during the production process; we recommend that it is post-added using a moderate shear force.
Due to its considerable rheological effectiveness, the additive can cause an immediate, very strong increase in viscosity and therefore make further processing more difficult. In this case, we recommend prediluting with water (10 parts RHEOBYK-425 to 90 parts water). RHEOBYK-425 is highly viscous at low temperatures; predilution can also be helpful under these conditions. The storage stability of the diluted solutions should be tested on a case-by-case basis.

Properties

Physical Form
Typical Properties
ValueUnitsTest Method / Conditions
Flash Pointmin. 100°C-
SolventsPolypropylene glycol--
Refractive Index (at 20°C)1.46--
Density (at 20°C)1.04g/ml-
Active Substance50%-
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Auto Ignition Tempertauremin. 200.00°CDIN 51794
Flash Pointmin. 100.00°CPensky-Martens
Initial Boiling Pointmin. 200°CDerived
Melting Pointmax. 10°CDerived
Density (at 20°C, 1013 hPa)1.042g/cm³Oscillating U-tube
Vapor Pressure (at 25°C, Calculated)max. 1hPaDerived
AppearanceLiquid--
ColorLight yellow--
Miscible inWater--
OdorCharacteristic--
pH (at 20°C, Concentration: 1%)7-Universal pH-Value Indicator
Composition Data

Solution of a urea-modified polyurethane

Regulatory & Compliance

OEM Specifications

Storage & Handling

Storage and Transportation

It is preferable to store RHEOBYK-425 at temperatures between 10 °C and 40 °C. Depending on the storage conditions, the additive can appear non-homogeneous; there is no known influence on the rheological effectiveness. Mix well before use.