Trigonox® 178 is a solution of methyl ethyl ketone peroxide and cumyl hydroperoxide in 2,2,4-trimethyl-1,3-pentanediol diisobutanoate. It serves as a curing agent and initiator for various polymer systems. This liquid solution is compatible with vinyl esters, thermosetting acrylics, and unsaturated polyesters (UPE). It is commonly used in the production of laminates and cast polymers. Trigonox® 178 is registered in multiple chemical inventories, including Switzerland (CHINV), Japan (ENCS), the Philippines (PICCS), China (IECSC), Canada (DSL), Japan (ISHL), Korea (KECI), the USA (TSCA), and Australia (AICS).

Chemical Name: 2-Butanone peroxide, Cumene hydroperoxide

CAS Number: 80-15-9, 1338-23-4

Chemical Family: Peroxides

Compatible Polymers & Resins: Thermosetting Acrylics, Unsaturated Polyester (UPE), Vinyl Esters

Enhanced TDS

Identification & Functionality

Applications & Uses

Compatible Polymers & Resins
Plastics & Elastomers End Uses
Thermal stability

Organic peroxides are thermally unstable substances, which may undergo self-accelerating decomposition. The lowest temperature at which self- accelerating decomposition of a substance in the original packaging may occur is the Self-Accelerating Decomposition Temperature (SADT). The SADT is determined on the basis of the Heat Accumulation Storage Test.
For Trigonox 178 SADT : 60°C (140°F)

Application Information

Trigonox 178 is a convenient pre-blended initiator suitable for curing unsaturated polyester, vinyl ester and acrylic thermosetting resins at ambient conditions in conjunction with a metal salt. Trigonox 178 produces lower exotherms than standard MEKP’s and is useful in warm and hot weather climates. Applications include cast polymer and laminates. Additional end-use information is available in various application sheets or directly from your AkzoNobel representative.

Properties

Physical Form
Appearance
Clear liquid (at 20 - 25°C)
Typical Properties
ValueUnitsTest Method / Conditions
Self-Accelerating Decomposition Temperature60°C-
Maximum Storage Temperature30°C-
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Oxidising PropertiesNot classified as oxidising--
AppearanceColorless liquid--
Organic Peroxides58 - 63%-
Active Oxygen Content9.1%-
Explosive PropertiesNot Explosive--
Self-Accelerating Decomposition Temperature60°CSADT
Decomposition TemperatureSADT - Self accelerating decomposition temperature is the lowest temperature at which self accelerating decomposition may occur with a substance in the packaging as used in transport. A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by thermal decomposition at and above the SADT. Contact with incompatible substances can cause decomposition below the SADT--
Insoluble inWater (at 20°C)--
OdorCharacteristic--
FlammabilitySolid and Gas--
Flash PointAbove the SADT value--
Boiling PointDecomposes below the boiling point--
Soluble inMost organic solvents--
Characteristics
ValueUnitsTest Method / Conditions
Active Oxygen Content9.1%-

Regulatory & Compliance

Safety & Health

Safety Information

Keep away from open fire, sparks and other sources of heat or ignition. Avoid contact with reducing agents (e.g. amines), acids, alkalis and heavy metal compounds (e.g. accelerators, driers and metal soaps). Please refer to the Material Safety Data Sheet (MSDS) for further information on the safe storage, use and handling of Trigonox 178. This information should be thoroughly reviewed prior to acceptance of this product.Keep away from open fire, sparks and other sources of heat or ignition. Avoid contact with reducing agents (e.g. amines), acids, alkalis and heavy metal compounds (e.g. accelerators, driers and metal soaps).

Packaging & Availability

Packaging Information

Trigonox 178 is packed in non-returnable, one gallon polyethylene containers of 8 lb net weight (4 per case).
Both packaging and transport meet the international regulations. For the availability of other packed quantities contact your AkzoNobel representative.
Trigonox 178 is classified as Organic peroxide type D; liquid; Division 5.2; UN 3105.

Storage & Handling

Shelf Life
3 years
Storage Information

Due to the relatively unstable nature of organic peroxides a loss of quality can be detected over a period of time. To minimize the loss of quality, AkzoNobel recommends a maximum storage temperature (Ts max.) for each organic peroxide product.
For Trigonox 178 Ts max. = 30°C (86°F)
When stored under these recommended storage conditions Trigonox 178 will remain within the AkzoNobel specifications for a period of at least 3 months after delivery.